This paper presented the study of the mechanochemical activation powder mix in dry and liquid grinding media, accompanied by agglomeration of the particles. It Is shown that when agglomerate particles having a bimodal size distribution is forming during the treatment in a dry grinding media and partially (2 wt % ) decaying at grinding by pestle in mortar. The transition to liquid grinding media is leading to a unimodal size distribution and increasing dispersion of the agglomerated particles, characterized by secondary agglomerating when using the alcohol and destruction when using activation in saturated aqueous solution of boric acid. Inherited effect mechanical activation parameters on the compaction process during cold compaction and hot stamping has been determined. Application treated in a high energy mill in an grinding media saturated aqueous H3BO3 Al-Si powder mix results in the formation of moldings with low cold-pressing relative density (0.735) and the activation of the hot stamping compaction (|εh| = 0,592) providing production of hot-deformed powder material with increased mechanical properties.

Keywords: mechanochemical activation, hot-deformed powder material, aluminum, silicon, dispersion, agglomeration

The analysis of temperature dependence of frequencies of lines  is conducted active in the spectrums of combination dispersion of  perchlorate of natrium. The theory analysis of spectrums is conducted.

Keywords: Perchlorat of natrium, anion, spectrums of combination dispersion, phase change

The values  the frequencies of the stretching vibrations of anions  SCN-,  NO2-, NO3-, CℓO4- in molten salts of alkali metals and their point group symmetry. There is a correlation with an increase in the frequency of symmetry  

Keywords: Raman Spectra; anions; molten solts; group symmetry.