It is found that a sufficiently high catalytic activity of the metal oxide electrode is due to the state of phase disordering of the coating surface due to the presence of highly dispersed spinel-like and rutile-like phases of solid solutions, as well as the nature of the distribution of these phases in the coating volume. The possibility of formation of disordered and partially ordered spinel-like phases of the form (Co,Mn)3-xO4 is analyzed
Keywords: structural-phase disorder, solid solutions, spinalator phase retinopathy phase coating
This article presents the results of studies on the effect of the erbium chelate complex on the processing of secondary raw materials from polyethylene terephthalate (PET).
Keywords: polyethylene terephthalate, recycling, extrusion, polyisobutylene, chelate complex of erbium.
The article examines the effect of polytitanate potassium intercalated copper on the structure and physico-mechanical properties of composite materials containing as a filler. Matrix composite material is a mixture of polyethylene 277 and copper-polymer complex of polyacrylamide. It is shown that the pre-intercalation of polytitanate potassium copper improve of physico-mechanical properties of the composite material.
Keywords: intercalated, polytitanate potassium, polyethylene, copper-polymer complex of polyacrylamide, friction coefficient, wear resistance, structure, hardness, elemental composition
Effect of water-soluble polymers additive and surface treatment on particle size distribution are shown in this article.
Keywords: electrolytic copper powder, water-soluble polymer, polyvinylpyrrolidone, polyacrilamide, electropolishing, atomic force microscopy
The article presents a comparative analysis of nanopowders of copper obtained by electrolysis with the use of the stabilizer polyvinylpyrrolidone (PVP). It is established that the properties of powders of copper determines PVP polymer film formed on the surface of nanoparticles
Keywords: Nanopowders of copper, stabilization of particles, granulometric composition, differential thermal analysis, water-soluble polymer
In this article methods of copper ultrafine powders stabilization from agglomeration and aggregation by water soluble polymer in process of production by electrolysis on vibrating cathode, as well as their effect on physical and mechanical properties of polymer composites.
Keywords: ultrafine powders, stabilization, friction coefficient, wear, structure of composite materials
The effect of two surface-active substances (SAS) - polyvinylpyrrolidone (PVP) and polyacrilamide (PAA) on formation kinetics of anodic synthesized electrolytes for copper powders production was reviewed, as well as product properties. It was found that the copper powder properties defined by polymer film of PVP and PAA formed on cathode surface. Nanosized particles percentage increasing by dints of copper ions direct discharge from ammonia complex ions provided by polymer film. In the electrolyte containing PAA is possible to obtain copper powder with nanosized (less 100 nm) particles content of 50,2%, average size in nanosized range is 43nm with needle-dendrite particle shape
Keywords: electrolytic copper powder, vibrating cathode, polarization curve, chronopotentiometry, potential dip after current tripping, particle size distribution, water soluble polymer, nanosized particle, ammonia chloride, polyvinylpyrrolidone, polyacrilamide, am
Influence of the fluorinated surface-active substances entered info a solution of chemical nickel plating, on operational properties nickel-phosphoric of the coverings besieged from investigated structures (solutions) is considered.
Keywords: nickel-phosphoric of the covering; surface-active substances; operational properties